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The effect of caffeine on appetite regulation and energy intake is less clear and varies depending on timing and dose. errorContainer { background-color: #FFF; color: #0F1419; max-width. 4,548 likes. Symptoms of a caffeine allergy include: itchy skin. Caffeine (1,3,7-trimethylxanthine) belongs to a group of compounds called methylxanthines, which are primarily known for their stimulatory effects. Introduction. Caffeine is also available in prescription and non-prescription medications. Coffee may reduce the risk of liver damage (cirrhosis). For some people, the symptoms above may also appear with withdrawal symptoms, but caffeine withdrawal is more likely show up as headache, fatigue, and difficulty concentrating. Caffeine is a major component of coffee, tea and chocolate and in humans acts as a central nervous system (CNS) stimulant. 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